The shirt has previously been worn by many Liverpool greats like John Barnes, Terry McDermott, Jan Molby, and John Toshack.
Big move: Milan Jovanovic scores Serbia's winner against Germany at the World Cup
The Serbian will hope to do better than the last man who donned the shirt, Andriy Voronin.
The forward completed his transfer from Standard Liege last week.
The29-year-old was a free agent after his deal with the Belgian club expired at the end of last season.
Anfield favourites: John Barnes and Jan Molby both wore the No 10 shirt
He scored Serbia's winner in their surprise WorldCup victory over Germany in South Africa.
'It is an honour for me to sign for one of the biggest clubs in football,' he said after completing his move.
Torres dons Liverpool scarf in Spain's party amid fears he'll quit for ChelseaCavalieri closer to Anfield exit as Brazil duo track Liverpool's goalkeeperLIVERPOOL FC